Solid detonation
  • 22 Jul 2024
  • 2 Minutes to read

Solid detonation


Article summary

What is a Solid Detonation?

Solid detonation is a phenomenon where a solid material undergoes a rapid exothermic reaction, releasing a substantial amount of energy and generating a shock wave. This process is critical in various industries and applications, including chemical manufacturing, mining operations, and munitions production.

How does a Solid Detonation arise?

Solid detonations occur when a solid substance undergoes a chemical reaction that breaks down its molecular structure, releasing stored chemical energy. Key factors contributing to the initiation and propagation of solid detonations include:

Initiation: Solid detonations start with an initiation event that provides the energy needed for a rapid chemical reaction. This energy can come from mechanical impact, thermal heating, or electrical sparks and must exceed a certain threshold to trigger the reaction.

Propagation: Once initiated, the chemical reaction spreads through the solid at supersonic speeds. The release of energy from the reaction creates a high-temperature zone that drives further decomposition and energy release.

Shock wave generation: The rapid, exothermic reaction generates a high-pressure shock wave that travels through the material and into the surrounding medium, causing mechanical damage and imparting significant energy to the environment.

Characteristics of Solid Detonation

High energy release

Solid detonations release a large amount of energy in a short period, resulting in rapid expansion and the formation of a shock wave.

Shock save

The shock wave generated by solid detonation is characterized by high pressure and velocity, capable of causing structural damage and fragmentation of the surrounding environment.

Heat and fragmentation

Alongside the shock wave, solid detonations produce intense heat and can fragment the material, dispersing debris and enhancing the overall destructive potential.

Modelling Solid Detonations

One common modelling approach is based on a blast method that requires a TNT equivalency factor. This factor relates the explosive power of an accidental explosion to an equivalent TNT charge, presenting the mass of TNT that would produce the same degree of damage. This approach is used in Gexcon’s integral consequence modelling tool EFFECTS.

The TNT charge blast method is used to predict the blast effects and assess potential damage from a given amount of fuel. The TNT equivalency method for blasts is straightforward. The equivalent mass of TNT can be calculated as follows:

  • QTNT = Equivalent mass of TNT

  • αe = TNT equivalency based on energy

  • Qf = Mass of fuel involved

  • Emf = Combustion energy of fuel per unit mass

  • EmTNT = TNT blast energy per unit mass

  • αm = TNT equivalency based on mass

By determining the TNT charge weight, one can predict the blast characteristics in terms of peak side-on overpressure of the blast wave dependent on the distance to the charge and the corresponding damage pattern. For instance, these relationships can be referenced from a chart, as demonstrated below (Bosch, 2005).

Peak side-on overpressure due to surface TNT explosion according to Marshall (Bosch, 2005)

Conclusion

Solid detonation involves a rapid exothermic reaction within a solid material, releasing substantial energy and generating a high-pressure shockwave. This phenomenon is essential in industries such as chemical manufacturing, mining, and munitions. It initiates from energy sources like impact, heat, or sparks and propagates at supersonic speeds, causing significant mechanical damage. Modelling these explosions using TNT equivalency helps predict blast effects and assess potential damage accurately.


References

Bosch, C. v. (2005). Methods for the calculation of physical effects 'Yellow book' CPR 14E. The Hague: Ministerie van Verkeer en Waterstaat.


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